Electrochemical SystemsJohn Wiley & Sons, 27 nov 2012 - 672 páginas The new edition of the cornerstone text on electrochemistry Spans all the areas of electrochemistry, from the basicsof thermodynamics and electrode kinetics to transport phenomena inelectrolytes, metals, and semiconductors. Newly updated andexpanded, the Third Edition covers important new treatments, ideas,and technologies while also increasing the book's accessibility forreaders in related fields.
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Índice
PART A THERMODYNAMICS OF ELECTROCHEMICAL CELLS | 27 |
PART B ELECTRODE KINETICS AND OTHER INTERFACIAL PHENOMENA | 169 |
PART C TRANSPORT PROCESSES IN ELECTROLYTIC SOLUTIONS | 269 |
PART D CURRENT DISTRIBUTION AND MASS TRANSFER IN ELECTROCHEMICAL SYSTEMS | 369 |
APPENDIX A PARTIAL MOLAR VOLUMES | 603 |
APPENDIX B VECTORS AND TENSORS | 605 |
APPENDIX C NUMERICAL SOLUTION OF COUPLED ORDINARY DIFFERENTIAL EQUATIONS | 611 |
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activity coefficients anode applied approximation binary electrolyte boundary conditions calculated cathode cell potential Chapter charge density chemical potential chloride cm²/s composition concentration gradients concentration overpotential concentration profiles conductivity constant convection current density current distribution depends diffusion coefficient diffusion layer dilute solutions dimensionless disk electrode distance double layer effect electric field electrochemical potential Electrochemical Society electrochemical systems Electrochemistry electrode potential electrode reaction electrode surface electrolyte electrolytic solution electroneutrality energy equilibrium exchange current density expression Figure flow fluid flux density H₂O interface ionic ions John Newman Journal Laplace's equation limiting current mass transfer mass-transfer measured mercury metal migration molality molar number of species ohmic potential drop oxygen parameter phase porous electrode potential difference problem Pt(s reactant reference electrode region Reproduced from reference rotating disk Schmidt number Section semiconductor solvent supporting electrolyte surface overpotential Tafel temperature thermodynamic transference number variation velocity zero