Changes of StateN. Hannay Springer US, 1 may 1975 - 600 páginas The last quarter-century has been marked by the extremely rapid growth of the solid-state sciences. They include what is now the largest subfield of physics, and the materials engineering sciences have likewise flourished. And, playing an active role throughout this vast area of science and engineer ing have been very large numbers of chemists. Yet, even though the role of chemistry in the solid-state sciences has been a vital one and the solid-state sciences have, in turn, made enormous contributions to chemical thought, solid-state chemistry has not been recognized by the general body of chemists as a major subfield of chemistry. Solid-state chemistry is not even well defined as to content. Some, for example, would have it include only the quantum chemistry of solids and would reject thermodynamics and phase equilibria; this is nonsense. Solid-state chemistry has many facets, and one of the purposes of this Treatise is to help define the field. Perhaps the most general characteristic of solid-state chemistry, and one which helps differentiate it from solid-state physics, is its focus on the chemical composition and atomic configuration of real solids and on the relationship of composition and structure to the chemical and physical properties of the solid. Real solids are usually extremely complex and exhibit almost infinite variety in their compositional and structural features. |
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Términos y frases comunes
alloy antiferromagnet approximation atoms behavior binary boundary cal/g-atom calculations Chem chemical classical models clustering coarsening coefficient coherent compositional change concentration configurations convection critical exponents critical phenomena critical point curve deposition diffusion dimensionality dimer dislocations elastic entropy equation equilibrium experimental ferroelectrics ferromagnet field H first-order fluctuations free energy function given gradient grain grain-boundary growth rate Hamiltonian Heisenberg model interactions interface Ising model isothermal kinetics lattice linear liquid long-range magnetic martensitic matrix melt metastable method miscibility gap nucleation obtained order parameter ordering field parent phase particle phase diagram phase line Phase Transformations phase transition Phys product phases reaction region rotation Section series expansions shown in Figure solid solutions solid-state specific heat spherical model spin spinodal decomposition staggered field strain energy structure superfluid surface temperature theory thermal thermochemical thermodynamic tion Trans tricritical point unit volume values vertex configurations zero αβ
Referencias a este libro
Survey of Progress in Chemistry, Volumen 8 Arthur F. Scott No hay ninguna vista previa disponible - 1977 |
Mercury Cadmium Telluride Robert K. Willardson,Albert C. Beer No hay ninguna vista previa disponible - 1981 |