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when heated to certain temperatures. Some substances were known to be peculiarly adapted to this purpose, such as lumps of lime, and for many years the calcium light or "lime-light" as it is popularly called, had been in use for special purposes, and was the most intense light known. This light is made by heating a block of lime to the highest practicable temperature by means of a blast of oxygen and coal gas; but such lights were too complicated and expensive for general purposes. It had been determined even as early as the beginning of the nineteenth century, however, that the high temperature necessary for producing this light was due in part at least to the fact that such a large amount of material had to be raised to incandescence. It was evident, therefore, that if a small amount of some such substance as lime and magnesia could be spread out so as to present a large surface in a small space, such as is represented by basket-work, sufficient heat for making it incandescent might be obtained from an orr'inary gas-and-air blowpipe.

Here then was the germ of the "mantle" idea; and such an apparatus, known as the Clamond mantle, which was made of threads of calcined magnesia, was shown at the Crystal Palace Exhibition, in London, in 1882. Curiously enough, this mantle and burner worked in an inverted position, the mantle being suspended bottom upwards below the burner through which the blast of gas was forced. The light given by this mantle was most brilliant-little short of the older calcium light, in fact-but the device itself was too complicated to be of service for ordinary lighting [209]

VOL. VI.-14

purposes. The principle was correct, but the construction of the mantle was defective.

Meanwhile a German scientist, Dr. Auer von Welsbach, who had become famous in the scientific world for his researches on rare metals, was experimenting with certain oxides of different metals, and developing a method of handling them that finally resulted in the perfected incandescent burner in use at present. His process, which in theory at least was not entirely original with him, was to dip an open fabric of cotton into a solution of the nitrates of the metals to be used, drying it, and converting the nitrates into oxides by burning; the cotton fabric disappearing but leaving the skeleton of the oxide, which retained its original shape.

At the same time corresponding improvements were made in the type of burner, which is quite as essential to success as the mantle itself. It had been found that it was absolutely essential for such a burner to give a practically non-luminous flame, as otherwise the deposit of carbon particles will ruin the mantle. Two ways of obtaining this are possible; one by mixing a certain quantity of air with the gas before combustion, the other to burn the gas in so thin a flame that the air permeates it freely. Several burners of both types were used at first, but gradually the burners in which the air is mixed with the gas became the more popular, and most of the incandescent burners now on the market are of

this type.

In the construction of mantles at the present time, while the principle of their use remains the same as that of the lime-light, lime itself is not used, the oxides of

certain other metals having proved better adapted for the purpose. Thus the Welsbach patent of 1886 covered the use of thoria, either alone or mixed with other substances such as zirconia, alumina, magnesia, etc.; thoria being considered as having a very high power of light emission. Later it was discovered that pure thoria emits very little light by itself, although it possesses a refractory nature that gives a stability to the mantle unequalled by any other material as yet discovered. When combined with a small trace of the oxides of certain rare metals, however, such as uranium, terbium, or cerium, thoria mantles have a very high power of light emission, most modern mantles being composed of about ninety-nine per cent. thoria with one per cent. cerium.

In the ordinary method of manufacturing such mantles, a cotton-net cylinder about eight inches long, more or less according to the size of mantle required, is made, one end being contracted by an asbestos thread. A loop of the same material, or in some cases a platinum wire, is fastened across the opening, to be used for suspending the mantle when in use. The cotton-thread cylinder is soaked in a solution of the nitrates of the metals thorium and cerium, and is then wrung out to remove the excess, stretched on a conical mold, and dried. The flame of an atmospheric burner being applied to the upper part at the constricted position, the burning extends downward, converting the nitrates into oxides, and removing the organic matter. Considerable skill is required in this part of the process, as the regular shape of the mantle is largely dependent

upon the regularity of the burning. As a finishing process a flame is applied to the inside of the mantle after it has cooled, to remove all traces of carbon that may remain.

The mantle is now ready for use, but is so fragile that it can scarcely be touched without breaking, and such handling as would be necessary for shipment would be out of the question. It is therefore strengthened temporarily by being dipped into a mixture of collodion and castor oil, which, when dry, forms a firm but elastic jacket surrounding all parts. It is this collodion jacket that is burned away when the new mantle is placed on the burner before the gas is turned on.

Quite recently the method of manufacturing mantles used by Clamond has been revived. In this method the cotton thread is dispensed with, the thread used being made from a paste containing the mantle material itself. The paste is placed in a proper receptacle the bottom of which is perforated with minute openings, and subjected to pressure, squeezing out the material in long filaments. When dry these are wound on bobbins, and, after being treated by certain chemical processes, are ready for weaving into mantles. It is claimed for mantles made on this principle that they last much longer and retain their light-emitting power more uniformly than mantles made by the older process.

THE INTRODUCTION OF ACETYLENE GAS

When the incandescent mantle had been perfected so as to be an economical as well an as efficient lightgiver, the position of coal gas as an illuminant seemed

again secured against the encroachments of its rivals, the arc and incandescent electric lights. But just at this time another rival appeared in the field that not only menaced the mantle lamp but the arc and incandescent light as well. Curiously enough, this new rival, acetylene gas, had been brought into existence commercially by the electric arc itself. For although it had been known as a possible illuminant for many years, the calcium carbide for producing it could not be manufactured economically until the advent of the electric furnace, itself the outcome of Davy's arc light.

Even as early as 1836 an English chemist had made the discovery that one of the by-products of the manufacture of metallic potassium would decompose water and evolve a gas containing acetylene; and this was later observed independently from time to time by several chemists in different countries. No importance was attached to these discoveries, however, and nothing was done with acetylene as an illuminant until the last decade of the nineteenth century. By this time electric furnaces had come into general use, and it was while working with one of these furnaces in 1892 that Mr. Thomas F. Wilson, in preparing metallic calcium from a mixture of lime and coal, produced a peculiar mass of dark-colored material, calcium carbide, which, when thrown into water, evolved a gas with an extremely disagreeable odor. When lighted, this gas burned with astonishing brilliancy, and, as its cost of production was extremely small, the idea of utilizing it for illuminating was at once conceived and put into practice. The secret of the cheap manufacture of the carbide

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