The Same and Not the Same

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Columbia University Press, 1995 - 294 páginas

Positioned at the crossroads of the physical and biological sciences, chemistry deals with neither the infinitely small, nor the infinitely large, nor directly with life. So it is sometimes thought of as dull, the way things in the middle often are. But this middle ground is precisely where human beings exist. As Hoffmann shows in his inspired prose, the world observed at its molecular level is complex and agitated, as are the emotions of the supposedly dispassionate scientists who explore it. In The Same and Not the Same the vital tensions of chemistry are revealed; with down-to-earth explanations, Hoffmann uncovers the polarities that power, rend, and reform the world of molecules. When we wash an apple before eating it, we are thinking not merely of the dirt that may still be on it but of the pesticides used in agricultural production. When we take medication, we expect relief for our pain but also fear side effects. The Same and Not the Same shows this ambivalence to be only one of a number of dualities pervading the world of molecules. The theme of identity, reflected in the title of the book, is central to the story. Other dualities, from stasis and dynamics, to creation and discovery to the rich complexity of revealing and concealing, are lucidly delineated for nonscientist and scientist alike. The Same and Not the Same also offers a rare and compelling personal statement of the social responsibility of scientists. Unabashedly confronting some of the major ethical controversies in chemistry today, the book strives for balance in facing the pressing ecological and environmental concerns of our time.

 

Índice

Lives of the Twins
3
What Are You?
7
Whirligigs
11
Fighting Reductionism
18
The Fish the Worm and the Molecule
22
Telling Them Apart
25
Isomerism
26
Are There Two Identical Molecules?
32
Beneath the Surface
62
The Semiotics of Chemistry
65
Acknowledgments 283
74
Creation and Discovery
87
In Praise of Synthesis
94
Cubane and the Art of Making
101
The Aganippe Fountain
108
Out to Lunch
116

Handshakes in the Dark
36
Molecular Mimicry
44
PART TWO The Way It Is Told
53
The Chemical Article
55
Notes 261
56
And How It Came to Be That Way
58
Janus and Nonlinearity
124
The Social Responsibility of Scientists
139
Mechanism
148
Equilibrium and Perturbing
160
Fritz Haber
167
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Sobre el autor (1995)

Born in Zloczow, Poland, Roald Hoffmann escaped the annihilation of Polish Jews by the Germans during World War II and immigrated to the United States in 1949. He received a B.A. from Columbia University and a Ph.D. from Harvard University. While at Harvard, he and Robert Burns Woodward developed the Woodward-Hoffmann rules on the conservation of orbital symmetry during a chemical reaction by applying principles of quantum theory. These rules enabled scientists to predict an important class of organic reactions. Hoffmann went to work at Cornell University in 1965. In 1981 he shared the Nobel Prize for chemical reaction theory with Kenichi Fukui (who independently had developed an orbital theory in the 1950s).

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